UK Team ‘Solves’ Diesel NOx

Professor Hargrave (left) and Wilson led the team’s work

NOx emissions from diesels could be all but eliminated thanks to Loughborough Uni

ACCT is for Ammonia Creation and Conversion Technology

A simple, affordable and apparently foolproof solution to the problem that has led to the current worldwide ‘demonisation’ of diesel engines – emissions of life-limiting NOx – has been discovered by a team of British automotive research specialists working at Loughborough University.

The system, called ACCT (Ammonia Creation and Conversion Technology), has reached such a promising stage that the creators are being besieged by car manufacturers, component suppliers and even owners of large diesel fleets who have heard of the innovation on the grapevine and are desperate to use it to solve what they see as motoring’s most urgent problem.

The team – led by Graham Hargrave, professor of optical diagnostics, and Jonathan Wilson, research associate – has been working on exhaust emissions for many years but achieved its breakthrough in the past two. From its current state, ACCT should be fairly easy to engineer, the team believes, and could reach production inside two years “with the right support”.

In essence, the Loughborough system converts AdBlue, the universally available urea-based after-treatment, into a special, ammonia-rich ‘ACCT fluid’ under accurately controlled conditions in an exhaust-mounted chamber.

Like current selective catalytic reduction (SCR) systems, it then uses freed ammonia “literally to rip NOx apart”, leaving only nitrogen and water. The crucial difference between the systems is that ACCT fluid keeps working at high efficiency in low exhaust temperature conditions that challenge current systems.

Preliminary tests on a city-based stop-start Skoda taxi indicate that ACCT can capture 98% of exhaust-borne NOx, against 60% for the same car running a conventional EU6 system – even before researchers had a chance to ‘tune’ the ACCT system for best performance.

Experts with knowledge of the discovery are starting to talk in terms of “virtually zero-emission” diesel engines, and to cite ACCT as being even more important than the arrival of the common-rail diesel.

In the past decade, NOx has become an infamous problem. It springs from the fact that diesels become more efficient as they run hotter, but this heat increases their NOx output. The effect has led to rapidly rising awareness of NOx’s detrimental effect on health: current European research suggests it shortens 71,000 lives a year.

Since 2014, the practice of injecting diesel exhausts with AdBlue via SCR exhaust catalysts has proved effective in most situations and has dramatically lowered average NOx outputs. But as the Loughborough researchers point out, gaps in SCR’s effectiveness remain – notably when low exhaust temperatures prevent complete decomposition of AdBlue, such as when a vehicle is idling in traffic, especially in stop-start conditions. NOx outputs rise when SCR doesn’t function well, which is the root of recent reports that even new-car exhausts sometimes produce multiples of the permitted NOx levels.

As Hargrave explained, there’s deep irony in this. While NOx has hit the headlines, CO2 continues killing the planet. “NOx is serious,” he said, “but it’s really a point-source problem. It only matters in a tiny minority of locations. Solve it and you can get on with reducing CO2, which is important everywhere.”

Because of NOx, Europe’s diesel market is in near chaos. Sales of oil-burning cars have collapsed by 20%, pressurising margins and infrastructure. A swing to more CO2-heavy petrol vehicles means targets are being missed — at the very moment CO2 targets are about to tighten.

For light commercials, there’s no realistic prospect of reducing diesels in the short term. Market experts don’t believe buyers will entertain a rapid change to downsized petrol engines or hybrids.

For HGVs, it’s much worse. Whereas car engines are ‘dialled back’ on NOx and need only light doses of AdBlue, trucks need much more. In cold-exhaust conditions (winter, for example), the incomplete breakdown of AdBlue leaves damaging and almost immovable exhaust deposits in complex exhaust systems that reduce power and even immobilise trucks completely. Understandably, the market in defeat devices for HGVs is lively.

The Loughborough team says it now needs a heavyweight technology partner to take ACCT to production but is wary of ceding valuable intellectual property rights cheaply. Negotiations between the university’s IP specialists and prospective partners are in full swing. “Our sense is that we need a major supplier rather than a single manufacturer,” said Hargrave.

Whatever ACCT’s route to market, an increasing number of potential users are desperate to see it progress. It could lead to a whole new lease of life for diesels.

STEVE CROPLEY

 

HOW IT HAPPENED
If ACCT changes diesels, as seems likely, it will be because Jonathan Wilson decided to do a PhD at Loughborough. Graham Hargrave, his professor, explains: “We’ve known for ages there was a NOx problem with AdBlue and low temperatures. Jonathan had an idea that could solve it but needed the opportunity to develop it so we went to the university and organised an internal scholarship. He’d worked on a similar topic through his undergraduate years. That work made it clear that if anyone was going to solve this, it’d be Jonathan. So we said here’s the lab and the money. Just go and make it work. And he did…”